Jurgen Klopp will be looking for his side to bounce right back after a dismal defeat at bottom club Swansea last Monday, while Alan Pardew seeks a cup run to salvage the Baggies’ season.
After a dramatic Virgil van Dijk winner to squeeze past local rivals Everton in the last round, Klopp will be hoping for a more comfortable result this time around.
Baggies boss Alan Pardew has lead something of a revival at the Hawthorns, playing more expansive football than his predecessor Tony Pulis.
Two wins in his last three in all competitions has shown promise; and the former Palace gaffer will hope to extend that run to three in four and cause a major upset.
When is it?
The game is on Saturday January 27, kicking off at 7.45pm, at Anfield.
TV channel information
The game will be broadcast live on BT Sport 2, and you can also follow all the action as it comes on Mirror Football.
Live stream information
The match can be streamed live online, on the BT Sport app, but on the other hand you can follow the whole game via Mirror Football.
Klopp looks set to rest his big names, meaning a start for perhaps out-going Daniel Sturridge or Danny Ings, while doubts have been cast about Jordan Henderson and left back Alberto Moreno. Nathaniel Clyne is still sidelined injured.
West Brom will miss ex Tottenham man Nacer Chadli and midfielder James Morrison, who both lay atop of the treatment table, but apart from them, Pardew has a full squad to pick from.
January 22: Swansea City 1-0 Liverpool (Premier League)
January 14: Liverpool 4-3 Manchester City (Premier League)
January 5: Liverpool 2-1 Everton (FA Cup)
January 1: Burnley 1-2 Liverpool (Premier League)
December 30: Liverpool 2-1 Leicester City
January 20: Everton 1-1 West Brom (Premier League)
January 13: West Brom 2-0 Brighton (Premier League)
January 6: Exeter City 0-2 West Brom (FA Cup)
January 2: West Ham 2-1 West Brom (Premier League)
December 31: West Brom 1-1 Arsenal (Premier League)
Liverpool win: 3/10
West Brom win: 8/1
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