The 44-year-old made sure all eyes were on her thanks to a stunning gold gown, which glittered as she walked the red carpet.
Showing off her trim figure, the dress cinched in at her waist while the skirt featured a tasselled detail.
Her brown hair was worn cropped with a loose wave, while she accentuated her natural beauty with a bronze eye make-up.
She was joined on the carpet by her proud looking partner John-Joseph (JJ) Feild, 40.
Her co-star Dwayne 'The Rock' Johnson was also there looking very dapper in a baby blue suit.
Skyscraper follows the story of a former FBI agent who must rescue his family from a newly built skyscraper–the tallest in the world–after it is taken over by terrorists.
Dwayne plays the agent Will, while Eve plays his wife Sarah.
The premiere comes after Neve revealed she and JJ had adopted a son called Raynor.
Sharing a pose on Instagram, she wrote: “Sheer joy!!!!….So it’s been a secret up until now as JJ and I wanted to wait until it was official but we adopted a beautiful baby boy 5 months ago.
“His name is Raynor and we are madly in love with him. Our 6 year old son Caspian is over the moon and asks every morning “Can I hold my baby? Can I feed my baby? Can I play with my baby”. It’s the most incredible thing we’ve experienced.”
The Scream actress continued: “We’re so grateful for this beautiful light coming into our lives and we think of and are grateful to his birth family every day for such an incredible gift. This picture was taken moments after our adoption became official yesterday and I’ve been dying to share our news with you all!”
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