The singer, 39, cuddled up with 65-year-old Fawaz Gruosi during his De Grisogono brand’s party at the Cannes Film Festival.
Nicole, wearing a black lace gown, also planted a smacker on the tycoon’s cheek along with socialite Paris Hilton, 37.
The former Pussycat Doll singer attended the de Grisogono bash at Villa des Oliviers in the French town, held during the 71st annual film festival.
Nicole is currently dating Bulgarian tennis ace Grigor Dimitrov, 27, who was not at the bash on Tuesday night.
She was joined by Paris Hilton, who wore a beaded purple dress and duck egg blue fur shawl as she arrived with fiance Chris Zylka.
The couple – who became engaged in January this year – put on a loved up display on the red carpet, with Chris planting a kiss on his future wife's cheek and lips.
Alessandra, 37, wore a black plunging gown which featured long, sheer sleeves and cut out diamond detailing at her hip bones.
The dress then fell into a long skirt with train and an obligatory thigh high split.
Winnie also got the split memo, flashing her pins in a red dress which featured a peplum waist detail and off the shoulder neckline.
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